Adaptive Injection Phasing and Methanol Blend Optimization for Low- Carbon Engine Performance: A Meta- Analysis and Machine-Learning Framework with CCS Integration

Authors

  • Luke Ajuka University of South Africa Author
  • Christopher Enweremadu University of South Africa Author

DOI:

https://doi.org/10.70917/jcc-2026-015

Keywords:

Decarbonization, Carbon capture and storage, Physics informed machine learning, Combustion ignition engines, SOI optimization, Sensitivity analysis

Abstract

The transition to net-zero mobility, aligned with global decarbonization targets, has intensified interest in methanol as a clean combustion fuel and carbon-neutral energy carrier. When optimally blended, methanol’s high-octane rating, strong charge-cooling effect, and inherent oxygen content enhance brake thermal efficiency (BTE), improve premixed combustion, and suppress knock in both spark- and compression-ignition engines. This study integrates meta-analysis, physics-informed modelling, and machine learning to establish predictive relationships between methanol blend ratio, start-of-injection (SOI) phasing, and engine performance. Meta-analysis revealed a significant positive correlation between SOI advancement and BTE (r = 0.74, 95% CI: 0.60–0.85), with moderate heterogeneity (I² = 38–45%). Optimal performance was achieved at methanol blend ratios of 25–30% with SOI between −30° and −35° CA aTDC, balancing efficiency gains with emission constraints. Quantitative model evaluation demonstrated high predictive accuracy (R² ≈ 0.99, RMSE < 0.30), exceeding typical machine learning combustion models (R² ≈ 0.91–0.97). SHAP-based sensitivity analysis confirmed that methanol blend ratio (0.125 ± 0.015) and SOI (0.082 ± 0.010) are dominant parameters controlling system behaviour. Model comparison showed that XGBoost achieved the highest accuracy (MAE = 0.01 °CA, RMSE = 0.02 °CA, R² = 0.985), outperforming Random Forest (R² = 0.90) and the physics-informed correlation model (R² = 0.93), while linear regression exhibited inferior performance (R² = 0.90) due to its inability to capture nonlinear interactions. Residual analysis (±0.4 BTE) and validation with 95% confidence bands (±0.42 BTE) confirmed strong predictive reliability and generalisation. The integration of carbon capture and utilization (CCU) pathways with methanol synthesis further supports closed-loop CO₂ utilisation, reinforcing methanol’s potential in carbon-neutral and carbon-negative applications. Overall, the findings highlight the importance of adaptive, AI-driven SOI optimisation and integrated CCU strategies for advancing next-generation low-emission engine systems.

References

Razak, T.R., Alaoui, A.E., Jarimi, H., Ul-Saufie, A.Z., Ismail, M.H. and Fuzi, M.F.M., 2025. ‘An AI-based hybrid Prophet–LSTM model for forecasting and financial optimisation in sustainable energy grids’. Artificial Intelligence for Sustainable Cities, 1(1), pp.42–60. doi:10.65582/aifsc.2026. 004.

Riffat, S., Oliveira, A., Jarimi, H., Razak, T.R., Riffat, J. and Chen, Z., 2026. ‘Editorial: Advancing energy access, innovation, and sustainability’. Energy Catalyst, 2, pp.1–3. doi:10.65582/ec.2026. 001.

Bakhsh, B.J. and Cantino, G., 2025. ‘European hydrogen valleys as catalysts for systemic decarbonization: A sustainability-oriented innovation and multi-level perspective analysis’. Green Technology and Innovation, 1(2), article 025330012. doi:10.36922/GTI025330012.

Shen, Y. and Yang, H., 2026. ‘Performance analysis of indoor CO₂ capture methods across operational contexts for building emissions reduction’. Global Decarbonisation, 2, pp.1–19. doi:10.65582/gd.2026.002.

Olah, G., Mathew, T., Goeppert, A. and Prakash, G., 2018. ‘Difference and significance of regenerative versus renewable carbon fuels and products’. Topics in Catalysis, 61, pp.1–8. doi:10.1007/s11244-018-0964-8.

Bos, M.J., Kersten, S.R.A. and Brilman, D.W.F., 2020. ‘Wind power to methanol: Renewable methanol production using electricity, electrolysis of water and CO₂ air capture’. Applied Energy, 264, article 114672. doi:10.1016/j.apenergy.2020.114672.

Berber, A., 2019. ‘The effect of diesel–methanol blends with volumetric proportions on the performance and emissions of a diesel engine’. Mechanika, 25(5), pp.363–369. doi:10.5755/ j01.mech.25.5.22954.

Duan, X., Feng, L., Liu, H., Jiang, P., Chen, C. and Sun, Z., 2023. ‘Experimental investigation on exhaust emissions of a heavy duty vehicle powered by a methanol fuelled spark ignition engine under world harmonized transient cycle and actual on road driving conditions’. Energy, 282, article 128869. doi:10.1016/j.energy.2023.128869.

Karvounis, P., Theotokatos, G., Vlaskos, I. and Hatziapostolou, A., 2023. ‘Methanol combustion characteristics in compression ignition engines: A critical review’. Energies, 16(24), article 8069. doi:10.3390/en16248069.

Zhen, X. and Wang, Y., 2015. ‘An overview of methanol as a fuel for internal combustion engines’. Renewable and Sustainable Energy Reviews, 52, pp.477–493. doi:10.1016/j.rser.2015.07.083.

Wu, Z., Xu, G., Ge, S., Yang, Z., Xue, X., Chen, H. 2024. ‘An efficient methanol pre-reforming gas turbine combined cycle with integration of mid-temperature energy upgradation and CO2 recovery: Thermodynamic and economic analysis’, Applied Energy, 358, article 122599. doi:10.1016/j.apenergy.2023.122599.

Vitillo, J.G., Eisaman, M.D., Aradóttir, E.S.P., Passarini, F., Wang, T. and Sheehan, S.W., 2022. ‘The role of carbon capture, utilization, and storage for economic pathways that limit global warming to below 1.5 °C’. iScience, 25(5), article 104237. doi:10.1016/j.isci.2022.104237.

Scripps CO₂ Program, 2025. Scripps CO₂ data and research. Scripps Institution of Oceanography, UC San Diego. scripps.ucsd.edu.

Samavedam, A.S., CV, P., Sreekanth, M., P, T. and M, F., 2026. ‘Predictive modeling of energy and exergy effects from injector placement in HCCI engines running on diethyl ether and biogas using machine learning techniques’. Research and Reviews in Sustainability, 2(1), pp.62–84. doi:10.65582/rrs.2026.006.

Ajuka, L. and Enweremadu, C. 2026. ‘Machine Learning-Driven Optimization of Atomization Characteristics in Fuel Blends Using Nanomaterials: Meta Analysis’. Materials Proceedings, 31(1), 29. https://doi.org/10.3390/materproc2026031029

International Energy Agency, 2021. Realising methanol’s potential as a motor fuel. Paris: IEA.

Xing, H., Stuart, C., Spence, S. and Chen, H., 2021. ‘Alternative fuel options for low carbon maritime transportation: Pathways to 2050’. Journal of Cleaner Production, 297, article 126651. doi:10.1016/j.jclepro.2021.126651.

Yao, A. and Yao, C., 2023. ‘Study of diesel/methanol dual fuel combustion in CI engines and its practice in China’. International Journal of Automotive Manufacturing and Materials, 2(1), pp.1–12. doi:10.53941/ijamm0201002.

Germane, G.J., 1985. ‘A technical review of automotive racing fuels’. SAE Transactions, 94, pp.867–878. doi:10.4271/852129.

Bromberg, L. and Cheng, W.K., 2021. Methanol as an alternative transportation fuel in the US: Options for sustainable and/or energy secure transportation. Cambridge, MA: MIT, pp.1–79.

Methanol Institute, 2018. Methanol safety fact sheet. Washington, DC: Methanol Institute, pp.1–3.

Schröder, J., Müller Langer, F., Aakko Saksa, P., Winther, K., Baumgarten, W. and Lindgren, M., 2020. Methanol as motor fuel – Summary report. AMF Task 56 Report.

Kalwar, A., Singh, R.K., Gupta, A., Rajak, R., Gosakan, G. and Agarwal, A.K., 2023. ‘Combustion and performance evaluation of methanol fueled BS VI compliant light duty SI engine’. ASME Open Journal of Engineering, 2, article 041008. doi:10.1115/1.4063343.

Netzer, C., Seidel, L., Ravet, F. and Mauss, F., 2019. ‘Impact of surrogate formulation on 3D CFD engine knock prediction using detailed chemistry’. Fuel, 254, article 115626. doi:10.1016/ j.fuel.2019.115678.

Bradley, D., Morley, C., Gu, X.J. and Emerson, D.R., 2002. ‘Amplified pressure waves during autoignition: Relevance to CAI engines’. SAE Technical Paper, 2002-01-2868. doi:10.4271/2002-01-2868.

Keum, S. and Kuo, T.-W., 2019. ‘Damkohler number analysis on the effect of ozone on autoignition and flame propagation in internal combustion engines’. Journal of Energy Resources Technology, 141(11), article 112402. doi:10.1115/1.4043639.

Hayashi, S., Sakai, Y. and Tanaka, K., 2023. ‘A theoretical study on the relationship between pressure rise and the Damkohler number of end gas auto ignition in spark ignited engines’. Combustion Theory and Modelling, 27(4), pp.605–626. doi:10.1080/13647830.2023.2188259.

Rasaq, I., Al Attab, K.A., Enagi, I.I., Idroas, M.Y. and Mohamed, A.R., 2025. ‘Optimization of a cyclone combustor in flameless combustion using producer gas’. Green Technology and Sustainability, 3(2), pp.1–13. doi:10.1016/j.grets.2024.100154.

Otalvaro Marín, H.L. and Machuca Martínez, F., 2020. ‘Sizing of reactors by charts of Damkohler’s number for solutions of dimensionless design equations’. Heliyon, 6(11), article e05477. doi:10.1016/j.heliyon.2020.e05386.

Wijaya, W.Y., Shunsuke, K., Hirotatsu, W. and Ken, O., 2012. ‘Damkohler number as a descriptive parameter in methanol steam reforming and its integration with absorption heat pump system’. Applied Energy, 94, pp.141–147. doi:10.1016/j.apenergy.2012.01.041.

Attili, A., Bisetti, F., Mueller, M.E. and Pitsch, H., 2015. ‘Damkohler number effects on soot formation and growth in turbulent non premixed flames’. Proceedings of the Combustion Institute, 35(2), pp.1215–1223. doi:10.1016/j.proci.2014.05.084.

Wang, J., Tian, H., Zhang, R., Shen, B., Su, Y., Yu, H. and Zhang, Y., 2023. ‘Experimental investigation on the effects of direct injection timing on combustion, performance and emission characteristics of methanol/gasoline dual fuel DFSI engines under high load’. Energies, 16(24), article 47921. doi:10.3390/en16247921.

Stauch, R. and Maas U. 2008. ‘The ignition of methanol droplets in a laminar convective environment”, Combustion and Flame, 153 (1–2), pp. 45–57. doi:10.1016/j.combustflame.2007.09.002

Zhen, X., Wang, Y., Xu, S., Zhu, Y., Tao, C. and Xu, T., 2012. ‘The engine knock analysis – an overview’. Applied Energy, 92, pp.628–636. doi:10.1016/j.apenergy.2011.11.079.

Paltrinieri, S., Mortellaro, F., Silvestri, N., Medda, M., Corrigan, D. and Rolando, L., 2019. ‘Water injection contribution to enabling stoichiometric air to fuel ratio operation at rated power conditions of a high performance DISI single cylinder engine’. SAE Technical Paper, 2019-01-1148. doi:10.4271/2019-24-0173.

Bromberg, L. and Cheng, W., 2010. Methanol as an alternative transportation fuel in the US: Options for sustainable and/or energy secure transportation. Final Report. UT Battelle Subcontract No. 4000096701.

Wang, H., Ben, J., Zhang, S., Wang, K. and Xie, P. 2026. 'Green Methanol from CO2 Hydrogenation at Industrial Scale: Progress, Challenges, and Perspectives'. Chem & Bio Engineering. 3(2), pp. 159-178. doi: 10.1021/cbe.5c00113

Zhou, Y., Hong, W., Xie, F.-X., Li, X.-P., Su, Y. and Hu, Y.-B., 2022. ‘Potential of compression ratio and exhaust gas dilution for improving combustion and NOₓ emission performance of methanol fueled PFI engines’. Fuel, 323, article 124321. doi:10.1016/j.fuel.2022.124197.

Yu, H., Su, Y., Shen, B., Zhang, Y., Wang, B. and Zhou, Y., 2024. ‘Effect of direct methanol injection based on low flow injectors on knock under heavy load gasoline engine operation’. Fuel, 357, article 130111. doi:10.1016/j.fuel.2023.129899.

Rehage, H. and Kind, M., 2020. ‘The first Damkohler number and its importance for characterizing the influence of mixing on competitive chemical reactions’. Chemical Engineering Science, 229, article 116007. doi:10.1016/j.ces.2020.116007.

Xu, C., Bao, Y., Li, X., Qian, L. and Oppong, F., 2023. ‘Pressure fluctuation and cellularization characteristics of 2-ethylfuran spherical expanding flames’. Fuel, 349, article 128627. doi:10.1016/ j.fuel.2023.128627.

Geng, Z., Ding, C., Hu, J., Ampah, J.D., Jin, C. and Liu, H., 2025. ‘Stable inter solubility mechanisms of methanol–n heptane blends assisted by co solvents: Quantum chemical insights’. Journal of Molecular Liquids, 417, article 126626. doi:10.1016/j.molliq.2024.126626.

Li, S.-H., Wen, Z., Hou, J., Xi, S., Fang, P., Guo, X., Li, Y., Wang, Z. and Li, S., 2022. ‘Effects of ethanol and methanol on the combustion characteristics of gasoline using a revised variation disturbance method’. ACS Omega, 7(21), pp.17797–17810. doi:10.1021/acsomega.2c00991.

Methanol Institute, 2020. Methanol: An emerging energy resource for the 21st century. Policy Report.

Yates, A., Bell, A. and Swarts, A., 2010. ‘Insights relating to the autoignition characteristics of alcohol fuels’. Fuel, 89, pp.83–93. doi:10.1016/j.fuel.2009.06.037.

Wang, C.-M., Li, Y.-F., Xu, C.-S., Badawy, T., Sahu, A. and Jiang, C.-Z., 2019. ‘Methanol as an octane booster for gasoline fuels’. Fuel, 248, pp.76–84. doi:10.1016/j.fuel.2019.02.128.

Liu, Z., Zhang, Z., Rao, S. and Zheng, Z., 2024. ‘Study of water injection for suppressing knock in high compression ratio supercharged hybrid gasoline engines’. Energy, 287, article 129579. doi:10.1016/j.energy.2023.129702.

Wei, Y., Zhu, Z., Liu, S., Liu, H., Shi, Z. and Zeng, Z., 2023. ‘Injection strategy effects on mixture formation and combustion in heavy duty spark ignition methanol engines’. Fuel, 334, article 126688. doi:10.1016/j.fuel.2022.126680.

Duan, Q., Yin, X., Wang, X., Kou, H. and Zeng, K., 2022. ‘Knock combustion and direct injection effects in high compression ratio methanol engines’. Fuel, 311, article 122587. doi:10.1016/ j.fuel.2021.122505.

Miganakallu, N., Yang, Z., Rogóż, R., Kapusta, Ł.J., Christensen, C., Barros, S. and Naber, J., 2020. ‘Effect of water–methanol blends on engine performance at borderline knock conditions in gasoline direct injection engines’. Applied Energy, 264, article 114750. doi:10.1016/j.apenergy.2020.114750.

Zhu, Z., Mu, Z., Wei, Y., Du, R., Guan, W. and Liu, S., 2022. ‘Cylinder to cylinder variation of knock and mixture formation effects in heavy duty spark ignition methanol engines’. Energy, 254, article 124235. doi:10.1016/j.energy.2022.124197.

Feng, H., Lai, K., Zheng, Z., Lin, S., Wu, X. and Tang, Q., 2024. ‘Effects of methanol direct injection and high compression ratio on the performance of spark ignition passenger car engines’. Fuel, 357, article 129901. doi:10.1016/j.fuel.2023.130052.

Shen, B., Su, Y., Yu, H., Zhang, Y., Lang, M. and Yang, H., 2023. ‘Experimental study on the effect of injection strategies on the combustion and emissions characteristics of a gasoline/methanol dual fuel turbocharged engine under high load’. Energy, 282, article 128870. doi:10.1016/j.energy.2023. 128925.

Lee, B., Lee, H., Lim, D., Brigljević, B., Cho, W., Cho, H.-S., Kim, C.-H. and Lim, H., 2020. ‘Renewable methanol synthesis from renewable H₂ and captured CO₂: How can power to liquid technology be economically feasible?’. Applied Energy, 279, article 11582. doi:10.1016/j.apenergy. 2020.115827.

Methanol Institute, 2019. Renewable methanol. Washington, DC: Methanol Institute.

Deka, T.J., Osman, A.I., Baruah, D.C. and Rooney, D.W., 2022. ‘Methanol fuel production, utilization, and techno economy: A review’. Environmental Chemistry Letters, 20(6), pp.3525–3554. doi:10.1007/s10311-022-01485-y.

Lyons, M., Durrant, P. and Kochhar, K., 2021. Reaching zero with renewables: Capturing carbon. Abu Dhabi: International Renewable Energy Agency, pp.1–108.

Cordero-Lanzac, T., Ramirez, A., Navajas, A., Gevers, L., Brunialti, S., Gandia, L.M., Aguayo, A.T., Sarathy, S.M. and Gascon, J., 2022. ‘A techno economic and life cycle assessment for the production of green methanol from CO₂: Catalyst and process bottlenecks’. Journal of Energy Chemistry, 68, pp.255–266. doi:10.1016/j.jechem.2021.09.045.

Giuliano, A., Freda, C. and Catizzone, E., 2020. ‘Techno economic assessment of bio syngas production for methanol synthesis: Focus on the water–gas shift and carbon capture sections’. Bioengineering, 7(3), article 70. doi:10.3390/bioengineering7030070.

Chen, Y., Li, H., Zhao, W., Zhang, W., Li, J., Li, W., Zheng, X., Yan, W., Zhang, W., Zhu, J., Si, R. and Zeng, J., 2019. ‘Optimizing reaction paths for methanol synthesis from CO₂ hydrogenation via metal–ligand cooperativity’. Nature Communications, 10(1), article 1885. doi:10.1038/s41467-019-09918-z.

Ren, M., Zhang, Y., Wang, X. and Qiu, H., 2022. ‘Catalytic hydrogenation of CO₂ to methanol: A review’. Catalysts, 12(4), article 403. doi:10.3390/catal12040403.

Liang, H., Zhang, G., Li, Z., Zhang, Y. and Fu, P., 2023. ‘Catalytic hydrogenation of CO₂ to methanol over Cu based catalysts: Active site profiling and reaction pathway exploration’. Fuel Processing Technology, 252, article 107995. doi:10.1016/j.fuproc.2023.107995.

Zhu, J., Su, Y., Chai, J., Muravev, V., Kosinov, N. and Hensen, E.J.M., 2020. ‘Mechanism and nature of active sites for methanol synthesis from CO/CO₂ on Cu/CeO₂’. ACS Catalysis, 10(19), pp.11532–11544. doi:10.1021/acscatal.0c02909.

Higham, M.D., Poh, Y.R., Catlow, C.R.A. and Krossing, I., 2025. ‘Mechanism of CO₂ conversion to methanol on a highly representative Cu/ZnO interface’. Journal of Catalysis, 446, article 115997. doi:10.1016/j.jcat.2025.115997.

Ye, J., Dimitratos, N., Rossi, L.M., Thonemann, N., Beale, A.M. and Wojcieszak, R., 2025. ‘Hydrogenation of CO₂ for sustainable fuel and chemical production’. Science, 387(6737), article adn9388. doi:10.1126/science.adn9388.

Kim, J., Yoo, Y., Kim, S., Beak, J., Oh, S.D., Lee, J. and Seo, M., 2024. ‘Design and assessment of a mobile carbon capture system: Energy and exergy analyses’. Energy Conversion and Management, 300, article 117934. doi:10.1016/j.enconman.2023.117934.

Dziejarski, B., Krzyżynska, R. and Andersson, K., 2023. ‘Current status of carbon capture, utilization, and storage technologies in the global economy: A technical assessment’. Fuel, 342, article 127776. doi:10.1016/j.fuel.2023.127776.

Wu, P.C. and Lin, C.Y., 2025. ‘Feasibility and cost benefit analysis of methanol as a sustainable alternative fuel for ships’. Journal of Marine Science and Engineering, 13(5), article 973. doi:10.3390/jmse13050973.

Methanol Institute, 2023. Marine methanol: Future proof shipping fuel. Washington, DC: Methanol Institute, pp.1–3.

Shuangchen, M., Mengxuan, W., Tingting, H., Huihui, S., Bin, Z., Dongli, L. and Weizhong, C., 2013. ‘Kinetic experimental study on desorption of decarbonization solution using the ammonia method’. Chemical Engineering Journal, 217, pp.22–27. doi:10.1016/j.cej.2012.11.098.

Zhang, M. and Guo, Y., 2014. ‘A comprehensive model for regeneration of CO₂ capture using aqueous ammonia solutions’. International Journal of Greenhouse Gas Control, 29, pp.22–34. doi:10.1016/j.ijggc.2014.07.010.

Djettene, R., Dubois, L., Duprez, M.E., De Weireld, G. and Thomas, D., 2024. ‘Integrated CO₂ capture and conversion to methanol: Techno economic and environmental assessment versus synthetic natural gas pathways’. Journal of CO₂ Utilization, 85, article 102879. doi:10.1016/ j.jcou.2024.102879.

Sajnani, S., Memon, M.A., Memon, S.A., Kumar, A., Mehvish, D., Mukarama, A.S., Zhou, W. and Liu, Y., 2025. ‘CO₂ to methanol conversion: A bibliometric analysis with insights into reaction mechanisms and recent advances’. Processes, 13(2), article 314. doi:10.3390/pr13020314.

Nathrath, P., Kroll, F., Karmann, D., Geißelbrecht, M. and Schühle, P., 2025. ‘Methanol production in a sustainable, mild, and competitive process: Concept launch and analysis’. Green Chemistry, 27(30), pp.9268–9279. doi:10.1039/D5GC01307K.

Li, S., Chen, R., Wang, J., Deng, S., Zhou, H., Fang, M., Zhang, H. and Yuan, X., 2024. ‘Solar thermal assisted direct capture of CO₂ from ambient air for methanol synthesis’. npj Materials Sustainability, 2(1), article 14. doi:10.1038/S44296-024-00014-Y.

Hanson, E., Nwakile, C. and Hammed, V.O., 2025. ‘Carbon capture, utilization, and storage (CCUS) technologies: Evaluating the effectiveness of advanced CCUS solutions for reducing CO₂ emissions’. Results in Surfaces and Interfaces, 18, article 100381. doi:10.1016/j.rsurfi.2024.100381.

Yang, N., Kang, F., Zhang, K., Zhou, Y. and Lin, W.-F., 2023. ‘A strategy for CO₂ capture and utilization toward methanol production at industrial scale: An integrated high efficiency process based on multi criteria assessment’. Energy Conversion and Management, 293, article 117030. doi:10.1016/j.enconman.2023.117516.

Khojasteh Salkuyeh, Y., Ashrafi, O., Mostafavi, E. and Navarri, P., 2021. ‘CO₂ utilization for methanol production – Part I: Process design and life cycle greenhouse gas assessment of alternative pathways’. Journal of CO₂ Utilization, 50, article 101608. doi:10.1016/j.jcou.2021.101608.

Battaglia, P., Buffo, G., Ferrero, D., Santarelli, M. and Lanzini, A., 2021. ‘Methanol synthesis through CO₂ capture and hydrogenation: Thermal integration, energy performance, and techno economic assessment’. Journal of CO₂ Utilization, 44, article 101400. doi:10.1016/j.jcou.2020. 101407.

Ugwu, A., Osman, M., Zaabout, A. and Amini, S., 2022. ‘Carbon capture, utilization, and storage in methanol production using dry reforming based chemical looping technology’. Energy & Fuels, 36, pp.9719–9735. doi:10.1021/acs.energyfuels.2c00620.

Ravikumar, D., Keoleian, G. and Miller, S., 2020. ‘Environmental opportunity cost of using renewable energy for carbon capture and utilization in methanol production’. Applied Energy, 279, article 115835. doi:10.1016/j.apenergy.2020.115770.

Borisut, P. and Nuchitprasittichai, A., 2019. ‘Methanol production via CO₂ hydrogenation: Sensitivity analysis and simulation based optimization’. Frontiers in Energy Research, 7, article 81. doi:10.3389/fenrg.2019.00081.

Herzog, H. and Vukmirovic, N., 1999. ‘CO₂ sequestration: Opportunities and challenges’. Paper presented at the Seventh Clean Coal Technology Conference, Knoxville, TN.

Moghanloo, R.G., Yan, X., Law, G., Roshani, S., Babb, G. and Herron, W., 2017. ‘Challenges associated with CO₂ sequestration and hydrocarbon recovery’. In: Recent advances in carbon capture and storage, pp.209 ff. doi:10.5772/67226.

Statista, 2020. Share of CO₂ captured globally. Statista Database.

Carlsson, I.Y., 2025. ‘World’s first commercial scale e methanol plant opens in Denmark’. Reuters, 7 August.

Carbon Recycling International (CRI), 2018. Emission to liquid technology. Carbon Recycling International.

Azarabadi, H. and Lackner, K.S., 2020. ‘Post combustion capture versus direct air capture in decarbonizing US natural gas power’. Environmental Science & Technology, 54, pp.5102–5111. doi:10.1021/acs.est.0c00161.

Aghel, B., Janati, S., Wongwises, S. and Shadloo, M.S., 2022. ‘Review of CO₂ capture using blended amine solutions’. International Journal of Greenhouse Gas Control, 119, article 103715. doi:10.1016/j.ijggc.2022.103715.

Asgharian, H., Marques, D.L., Iov, F., Liso, V., Nielsen, M.P., Thellufsen, J.Z., and Lund, H., 2024. ‘Cryogenic carbon capture for future carbon neutral societies’. International Journal of Greenhouse Gas Control, 135, article 103867. doi:10.1016/j.ijggc.2024.104161.

Ketabchi, R.M., Babamohammadi, S., Davies, W.G., Gorbounov, M. and Soltani, S.M., 2023. ‘Advances and challenges in carbon capture using bio based sorbents: A state of the art review’. Carbon Capture Science & Technology, 6, article 100087. doi:10.1016/j.ccst.2023.100087.

Li, G. and Yao, J., 2024. ‘Direct air capture (DAC) for achieving net-zero CO₂ emissions: Advances, applications, and challenges’. Eng, 5(3), pp.1298–1336. doi:10.3390/eng5030069.

Gonzalez Olmos, R., Gutierrez Ortega, A., Sempere, J. and Nomen, R., 2022. ‘Zeolite versus carbon adsorbents in carbon capture: Operational and life cycle comparison’. Journal of CO₂ Utilization, 55, pp.128–137. doi:10.1016/j.jcou.2021.101791.

Dai, Z. and Deng, L., 2024. ‘Membrane technologies for CO₂ capture and separation: Progress toward industrial application’. Separation and Purification Technology, 335, article 123456. doi:10.1016/j.seppur.2023.126022.

Meng, L., Zheng, J., Yang, R., Peng, S., Sun, Y., Xie, J. and Li, D., 2023. ‘Microseismic monitoring technologies and prospects for CCUS injection engineering’. Energies, 16, article 3101. doi:10.3390/en16073101.

Si, M. and Du, K., 2020. ‘Development of a predictive emissions model using a gradient boosting machine learning method’. Environmental Technology & Innovation, 20, article 101028. doi:10.1016/j.eti.2020.101028.

Yeneneh, K. and Sufe, G., 2026. ‘Experimental and ANN-based analysis of performance, combustion, and emission characteristics of a CI engine fueled with waste plastic oil-diethyl ether-diesel blends’. PLoS One, 21(2), article e0341627. doi:10.1371/journal.pone.0341627.

Guo, H., Başhan, V., Yu, C., Bolat, F., Demirel, H. and Tian, X., 2025. ‘Effect of methanol injection timing on performance of marine diesel engines and emission reduction’. Journal of Marine Science and Engineering, 13(5), p.949. doi:10.3390/jmse13050949.

Wu, T., Yao, A., Yao, C., Pan, W., Wei, H., Chen, C. and Gao, J., 2018. ‘Effects of diesel late injection on combustion and emissions of diesel/methanol dual fuel engines’. Fuel, 233, pp.317–327. doi:10.1016/j.fuel.2018.06.063.

Sequera, A.J., Parthasarathy, R.N. and Gollahalli, S.R., 2011. ‘Effects of fuel injection timing on biofuel combustion in diesel engines at partial load’. Journal of Energy Resources Technology, 133, article 022203. doi:10.1115/1.4003808.

Huang, G., Li, Z., Zhao, W., Zhang, Y., Li, J., He, Z., Qian, Y., Zhu, L. and Lu, X., 2020. ‘Influence of fuel injection strategies on combustion and emissions in intelligent charge compression ignition engines fueled with methanol and biodiesel’. Fuel, 274, article 117851. doi:10.1016/ j.fuel.2020.117851.

Yin, X., Yan, Y., Ren, X., Yu, L., Duan, H., Hu, E. and Zeng, K., 2025. ‘Effects of methanol energy substitution ratio and diesel injection timing in methanol/diesel dual fuel direct injection engines’. Fuel, 382(B), article 133773. doi:10.1016/j.fuel.2024.133773.

Kumar, D., Sonawane, U., Chandra, K. and Agarwal, A.K., 2022. ‘Experimental investigation of methanol fumigation via port fuel injection in preheated intake air of a single cylinder dual fuel diesel engine’. Fuel, 324, article 124340. doi:10.1016/j.fuel.2022.124340.

El Seesy, A.I., Waly, M.S., Alhassan Nasser, N.A. and El Zoheiry, R.M., 2022. ‘Improvement of combustion, emission, and stability characteristics of diesel–methanol blends using n decanol as a co solvent’. Scientific Reports, 12, article 20326. doi:10.1038/s41598-022-20326-0.

Li, Z., Wang, Y., Wang, Y., Yin, Z., Gao, Z., Ye, Z. and Zhen, X., 2022. ‘Effects of fuel injection timing and methanol split ratio in M/D/M strategies for diesel/methanol dual fuel direct injection engines’. Fuel, 325, article 124970. doi:10.1016/j.fuel.2022.124970.

Vargün, M., Yılmaz, I.T., Özsezen, A.N. and Sayın, C., 2025. ‘Combustion parameters and exhaust characteristics of diesel engines using alternative fuels at different start of injection and gas pilot proportions’. Processes, 13, article 3024. doi:10.3390/pr13093024.

Svensson, E., Tunér, M. and Verhelst, S., 2019. ‘Influence of injection strategies on engine efficiency in methanol partially premixed combustion engines’. SAE International Journal of Advances and Current Practices in Mobility, 2(2), pp.653–671. doi:10.4271/2019-24-0116.

Treacy, M., Xu, L., Fatehi, H., Kaario, O. and Bai, X.S., 2024. ‘Performance of a methanol fueled direct injection compression ignition heavy duty engine under low temperature combustion conditions’. Energies, 17(17), article 4307. doi:10.3390/en17174307.

Downloads

Published

2026-07-20

Issue

Section

Articles

How to Cite

Adaptive Injection Phasing and Methanol Blend Optimization for Low- Carbon Engine Performance: A Meta- Analysis and Machine-Learning Framework with CCS Integration. (2026). Journal of Climate Change, 12(2), 31. https://doi.org/10.70917/jcc-2026-015